Product Details
7553-56-2 Name |
|
Name |
Iodine |
Synonym |
IodineFlakes,99.998%;Iodine,Resublimed,99.5%;Iodine(Resublimed)ExtraPure;Iodine, 99+%;NLT99,5%orrefined;Iodinespheres,ultradry,-60mesh,99.999%(metalsbasis);Iodine, 0.1 N standard solution;Iodine, for analysis ACS, 99.8+% |
7553-56-2 Chemical & Physical Properties |
|
Melting point |
113 °C(lit.) |
Boiling point |
184.4±9.0 °C at 760 mmHg |
Density |
3.8±0.1 g/cm3 |
Molecular Formula |
I2 |
Molecular Weight |
253.809 |
LogP |
3.16 |
Exact Mass |
253.808914 |
Vapour density |
9 (vs air) |
Vapour Pressure |
0.5±0.4 mmHg at 25°C |
Index of Refraction |
1.788 |
Water Solubility |
0.3 g/L (20 ºC) |
7553-56-2 Description |
Iodine was discovered in 1811 by Bernard Courtois, and is classed among the rarer elements. Iodine is found naturally in seaweed, and is considered and generally recognized as safe substance by the US Food and Drug Administration (FDA). Iodine is a required element by many species, including humans. It has been recognized as preventative against goiter since 1819, and is used in iodized salt for this purpose. Iodine is also used as a dough oxidizer in commercial bread making. Iodine is generally extracted from natural and oil field brines by means of oxidation of iodide with chlorine, then removal from solution with an airstream. Iodine is reabsorbed in solution and reduces to hidrotic acid with sulfur dioxide. The solution is then chlorinated to precipitate free iodine, and is further purified by treatment with concentrated sulfuric acid. Iodine is the heaviest essential element for most life, with tungsten being used by some bacteria. |
7553-56-2 Uses |
|
Two 'hollow' B-site deficient perovskites, (TzH)11(H3PO2)Sn6I23 and (TzH)3Sn2I7 (TzH+ = 1,2,4-triazolium, H3PO2 = hypohosphorous acid), have been prepared. (TzH)11(H3PO2)Sn6I23 is the first example of a 2D layered structure of this type. Leaving the same reaction mixture for an extended time also affords the 3D derivative (TzH)3Sn2I7.
A new class of layered alkali metal-MoO//3 bronzes, A//xMoO//3 (A equals Li, Na, K, Rb), with nearly the same unit cell parameters as the host oxide has been synthesized. This was accomplished by the solid state reaction of MoO//3 with alkali metal iodides around 575 K; Li//xMoO//3 absorbs H//2O causing an increase in the b parameter of the unit cell. Hexagonal potassium bronzes of W//1// minus //xMo//xO//3 are synthesized for the first time.
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