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49851-31-2

  • Product Name2-BROMO-1-PHENYL-PENTAN-1-ONE
  • Molecular FormulaC11H13BrO
  • Purity99%
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  • CasNo: 49851-31-2
  • Molecular Formula: C11H13BrO
  • Purity: 99%

Pharmaceutical Intermediates 2-BROMO-1-PHENYL-PENTAN-1-ONE 49851-31-2

49851-31-2 Name

Name

2-Bromo-1-phenyl-1-pentanone

Synonym

alpha-bromovaleropheone;2-Bromo-1-phenyl-1-pentanone, 2-Bromovalerophenone;2-BROMO-1-PHENYL-PENTAN-1-ONE;2-BroMovalerophenone;China 2-bromo-1-phenylpentan-1-one;2-Bromo-1-Phenyl-1-Pentanone CAS 49851-31-2 kf-wang(at)kf-chem.com;2-BROMO-1-PHENYL-1-PENTANONE;2-Bromovalerophenone alpha Bromovalerophenone

 

 

2-BROMO-1-PHENYL-PENTAN-1-ONE 49851-31-2 In Bulk Supply

49851-31-2 Chemical & Physical Properties

Boiling point

282.3±13.0 °C at 760 mmHg

Density

1.3±0.1 g/cm3

Molecular Formula

C11H13BrO

Molecular Weight

241.124

Flash Point

42.5±7.2 °C

PSA

17.07000

LogP

3.60

Exact Mass

240.014969

Index of Refraction

1.541

Vapour Pressure

0.0±0.6 mmHg at 25°C

 

49851-31-2 Uses

Valerophenone (V091450) derivative.

 

 

49851-31-2 Relevant articles

 

 

Enantioconvergent Cu-Catalyzed Radical C-N Coupling of Racemic Secondary Alkyl Halides to Access α-Chiral Primary Amines

 

Cheng, Jiang-Tao,Dong, Xiao-Yang,Gu, Qiang-Shuai,Li, Zhong-Liang,Liu, Juan,Liu, Xin-Yuan,Luan, Cheng,Wang, Fu-Li,Wang, Li-Lei,Yang, Ning-Yuan,Zhang, Yu-Feng

supporting information, p. 15413 - 15419 (2021/09/30)

α-Chiral alkyl primary amines are virtually universal synthetic precursors for all other α-chiral N-containing compounds ubiquitous in biological, pharmaceutical, and material sciences.

 

 

Synthesis of α,β-dibromo ketones by photolysis of α-bromo ketones with N-bromosuccinimide: Photoinduced β-bromination of α-bromo ketones

 

Moon, Da Yoon,An, Sejin,Park, Bong Ser

, (2019/10/28)

Irradiation of α-bromopropiophenones in the presence of NBS results in the formation of α,β-dibromopropiophenones, which can be viewed as β-bromination of α-bromopropiophenones. The reaction is believed to go through a series of reactions; photoinduced C–Br bond cleavage, elimination of HBr to give α,β-unsaturated ketone intermediates, and addition of Br2, which are formed by the reaction between HBr and NBS.

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