Product Details
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3475-39-6 Name |
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Name |
1,1,3-Tribromoacetone |
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Synonym |
1,1,3-TribromoAceton;2-Propanone,1,1,3-tribromo-;1,1,3-tribromoacetone;1,1,3-Tribromopropan-2-one;JACS-3475-39-6;TIANFU-CHEM--1,1,3-Tribromoacetone |
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3475-39-6 Chemical & Physical Properties |
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Boiling point |
266.2±25.0 °C at 760 mmHg |
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Density |
2.6±0.1 g/cm3 |
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Molecular Formula |
C3H3Br3O |
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Molecular Weight |
294.767 |
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Flash Point |
115.1±9.7 °C |
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PSA |
17.07000 |
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LogP |
3.25 |
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Exact Mass |
291.773376 |
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Vapour Pressure |
0.0±0.5 mmHg at 25°C |
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Index of Refraction |
1.595 |
1,1,3-Tribromoacetone is a chemical compound that has been studied in various scholarly articles for its potential applications. One of its primary uses is as a reagent in organic synthesis. It can be used as a starting material for the synthesis of various compounds, such as halogenated ketones and aldehydes.
InChI:InChI=1/C3H3Br3O/c4-1-2(7)3(5)6/h3H,1H2
Reported herein is a desymmetrization-based synthetic approach to the fused polycyclic indole alkaloid reserpine. The centerpiece of the developed strategy features an internal desymmetrization process that enabled the use of a readily accessible and nonstereogenic reserpine E-ring precursor, in contrast to the synthesis-intensive and stereodefined E-ring intermediates employed in all past reserpine syntheses. Utilization of inexpensive reagents through an orchestrated sequence of carefully selected chemical transformations further highlight the overall effectiveness of the developed pathway.
A simple and efficient method for the preparation of α,α- dichloroketones, α,α-dibromoketones, and α,α- diiodoketones by oxyhalogenation of alkynes using oxone and KX (X = Cl, Br, or I) is described.
o- and p-Bromophenol have been synthezied from the reactions of 2,2'-(azo-2-phenoxypropane) with different concentrations of bromine in 68 and 88percent yields, respectively.
acetone
1,3-dibromoroacetone
1,1,3-tribromoacetone
1-bromoacetone
| Conditions | Yield |
|---|---|
|
With pyridinium hydrobromide perbromide; In methanol; at 20 - 45 ℃; for 0.25h; Yield given. Yields of byproduct given;
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1,1-dibromopropan-2-one
water
hydrogen bromide
1,3-dibromoroacetone
1,1,3-tribromoacetone
1-bromoacetone
| Conditions | Yield |
|---|---|
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Gleichgewicht;
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1,1-dibromopropan-2-one
1,3-dibromoroacetone
acetic acid
acetone
N-{4-[(2,4-dioxo-1,2,3,4-tetrahydro-pteridin-6-ylmethyl)-amino]-benzoyl}-L-glutamic acid
folic acid
pteroic acid
4-[(2,4-diaminopteridin-6-ylmethyl)methylamino]benzoic acid
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